MTL - From the Power of Space To the Heavens - Chapter 109 . It is said that there are two Title Douluo, but in fact, they are

Utsuro no Hako to Zero no Maria, or The Empty Box and The Zeroth Maria, tells the sinister story of Kazuki Hoshino, who is almost madly attached to his everyday life, and his antagonist Aya Otonashi, who suddenly transfers into his class—for the 13,118th time. She majestically announces to “break” him, without paying heed to anyone else around them.

The year 1847

When Ye Mo suddenly woke up, he realized that everything around him seemed to have changed: He has been transmigrated into the modern Earth where spiritual energy is scarce. His pretty master from his former world was nowhere to be seen. Most importantly, he found himself in the body of a young man who has been abandoned by his clan for an embarrassing reason…

- Description from Novelupdates

Lu Xiao had followed his master for eighteen years, excelling in both medicine and martial arts.After five years of military service, he returned to the city to search for his origins.Faced with flashes of knives and shadows of swords, he was decisive in killing, dominating everyone.When it came to the matters of the heart, he said, “Still… the Young Miss is the best.”